Crystallization of self-fluxes of the system K2O−P2O5−MeIII2O3−MeIIO (MeIII – Al, Bi; MeII – Mg, Ca, Sr, Co, Ni, Zn)

TitleCrystallization of self-fluxes of the system K2O−P2O5−MeIII2O3−MeIIO (MeIII – Al, Bi; MeII – Mg, Ca, Sr, Co, Ni, Zn)
Publication TypeJournal Article
Year of Publication2015
AuthorsStrutynska, NYu., Livitska, OV, Zatovsky, IV, Slobodyanik, MS
Abbreviated Key TitleDopov. Nac. akad. nauk Ukr.
DOI10.15407/dopovidi2015.05.138
Issue5
SectionChemistry
Pagination138-143
Date Published5/2015
LanguageUkrainian
Abstract

The crystallization of self-fluxes of the system K2O−P2O5−MeIII2O3−MeIIO (MeIII – Al, Bi; MeII – Mg, Ca, Sr, Co, Ni, Zn) (molar ratios K/P = 0,85−1,30, MeII/MeIII = 1,0, MeIII/P = 0,30, and the range of temperatures 1000–680 ºC) is investigated. The analysis of the influence of the nature of alkaline metals on the interaction in the self-flux MeI2O−P2O5−MeIII2O3−MeIIO (MeI – K, Cs; MeII – Mg, Ca, Sr, Co, Ni, Zn; MeIII – Al, Bi) is done. The obtained crystalline phases are determined, by using X-ray powder diffraction, IR spectroscopy, and optical microscopy.
KeywordsIR spectroscopy, optical microscopy, phosphates, self-flux
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